http://www.sky.fm/ (lower quality feeds for free, still very nice selection)
http://somafm.com/ (I am especially fond of the "Secret Agent" and "Space Station" channels)
http://www.radioparadise.com/ (great mix!)
http://www.monkeyradio.org/ (a very select hand-picked playlist of downtempo, nujazz, lounge and ambient electronica)
http://www.bluemars.org/ (All I can say is WOW. Need something perfect for after the club closes? Three channels of differing tempo to choose from.)